Palladium-Catalyzed Allyl Oxime from Allyloxycarbonyl Oxime
نویسندگان
چکیده
منابع مشابه
Palladium-catalyzed Heck-type reaction of oxime ether bearing a pendant vinyl iodide moiety.
A Pd(0)-catalyzed intramolecular Heck-type reaction of oxime ether has been developed, providing convenient access to heterocyclic oximes.
متن کاملBenzamide oxime
In the crystal structure of the title compound, C(7)H(8)N(2)O, mol-ecules are connected via inter-molecular N-H⋯O and O-H⋯N hydrogen bonds to form a two-dimensional supra-molecular structure. The oxime group has an E configuration and the dihedral angle between the mean planes of the benzene ring and the amidoxime grouping is 20.2 (3)°.
متن کاملN-heterocyclic carbene catalyzed synthesis of oxime esters.
A triazolium salt derived N-heterocyclic carbene catalyzes the redox esterification reaction between α-β-unsaturated aldehydes and oximes. The resulting saturated oxime esters were obtained in very good yields for a broad range of aliphatic, aromatic and heteroaromatic substrates.
متن کامل2,6-Dichlorobenzaldehyde oxime
In the title compound, C(7)H(5)Cl(2)NO, there are two mol-ecules in the asymmetric unit. The mol-ecules are essentially identical. Each mol-ecule is connected to a symmetry-related mol-ecule through an inversion center by O-H⋯N hydrogen bonds, building an R(2) (2)(6) graph-set motif.
متن کامل(E)-3,5-Dimethoxybenzaldehyde oxime
In the title compound, C(9)H(11)NO(3), the oxime grouping is twisted by 12.68 (6)° with respect to the dimethoxyl-benzene ring. In the crystal, mol-ecules are linked into an infinite [100] chain via O-H⋯N hydrogen bonds, instead of the more common oxime packing motif of dimers with an R(2) (2)(6) graph-set motif.
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ژورنال
عنوان ژورنال: Journal of Organic Chemistry Research
سال: 2015
ISSN: 2330-5231,2330-524X
DOI: 10.12677/jocr.2015.31012